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Synthesis and Properties of an Unusual New High-Symmetry Osmium−Palladium Carbonyl Cluster Complex

✍ Scribed by Adams, Richard D.; Boswell, Erin M.; Captain, Burjor


Book ID
121224894
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
725 KB
Volume
27
Category
Article
ISSN
0276-7333

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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,