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Cluster synthesis 44. The synthesis and structural characterization of an unusual new high nuclearity platinum-osmium cluster complex, Pt5Os6(CO)25

✍ Scribed by Richard D. Adams; Jeffrey E. Cortopassi; Zhaoyang Li


Publisher
Springer
Year
1995
Tongue
English
Weight
550 KB
Volume
6
Category
Article
ISSN
1040-7278

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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,