Synthesis and Properties of 4,5-Dimethylacridine and 1,4,5,8-Tetramethylacridine 1
β Scribed by NEWMAN, MELVIN S.; POWELL, WARREN H.
- Book ID
- 126004702
- Publisher
- American Chemical Society
- Year
- 1961
- Tongue
- English
- Weight
- 502 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
To a cold (-78'C) solution of 10 mmoles of the iithium derivative ( I ) , RI=CH3, in tetrahydrofuran 111 was added with stirring 1.06 g (10 mmoles) of benzonitrile. The resulting bright orange mixture was kept at -78 O C for 40 min, after which the bath was removed and stirring was continued for an
Chemical correlation between the title compounds (7 and 8) was performed. X-ray crystallographic analysis of the novel tetr&reth%e (7) proved the trans configuration of ( 7) and indirectly that of tetramethyl-TAD (8). The latter's chemical and-conformational behavior is examined and dTs.cussed.
## Abstract For Abstract see ChemInform Abstract in Full Text.