Synthesis and properties of 1,6-diazaphenalenes and their charge-transfer complexes with tetracyanoquinodimethane

✍ Scribed by Koichi Tamaki; Yasushi Morita; Jiro Toyoda; Hideki Yamochi; Gunzi Saito; Kazuhiro Nakasuji

• Book ID: 104257338
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 199 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)00980-5

✦ Synopsis

1,6-Diazaphenalene and its derivatives containing methyl, bromo, chloro, phenyl, and 2pyridyl substituents form charge-transfer complexes with TCNQ. Relatively highly electrical conductive complexes (0.1 Scm -1) with small activation energy around 0.05 eV was obtained.