✍ Scribed by Oishi, Tsutomu ;Fujimoto, Minoru
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A series of optically active __N__‐protected α‐aminoketones were synthesized via the Grignard reaction of the Weinreb amides of the __N__‐__tert__‐butoxycarbonyl amino acids. Reduction of the α‐aminoketones by sodium borohydride resulted in the corresponding 1,2‐amino alcohols. © 2003 W
Two types of optically active itaconamates, a-ethyl 3-N-((R)-a'-methylbenzyl)itaconamate (MBEI) and a-N-((R)-a'-methylbenzyl)/3-ethyl itaconamate (EMBI) were synthesized from itaconic anhydride, (R)-amethylbenzylamine and ethanol. Radical polymerizations of MBEI and EMBI were performed in bulk and i
Recently several groups have utilized chiral P-hydroxysulfoxides 2 lm4, via the corresponding P-ketosulfoxides 3, for the synthesis of optically active epoxides 4 and secondary alcohols 5. Both antipodes of the epoxide and alcohol are accessible from the same P-ketosulfoxide B by stereoselective red