Synthesis and Polymerization of N -(L-Menthylcarboxylatomethyl)maleimide
โ Scribed by Oishi, Tsutomu; Kamori, Akira; Fujimoto, Minoru
- Book ID
- 120450395
- Publisher
- Taylor and Francis Group
- Year
- 1992
- Tongue
- English
- Weight
- 651 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1060-1325
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๐ SIMILAR VOLUMES
N-(4-Tetrahydropyranyl-oxy-phenyl) maleimide (THPMI) was prepared and polymerized by radical or anionic initiators. THPMI could be polymerized by 2,2ะ-azobis(isobutyronitrile) (AIBN) and potassium tert-butoxide. Radical polymers (poly(THPMI)r) were obtained in 15-50% yields for AIBN in THF at 65ยฐC
Two types of optically active N-(c-menthoxycarbonyl-n-pentyl)maleimide (MPMI) and N-(L-menthoxycarbonyl-n-undecyl)maleimide (MUMI) were synthesized. Radical homopolymerizations of MPMI and MUMI were performed at 60ยฐC for 24 h to give optically active polymers. Radical copolymerizations of MPMI (M1)