Synthesis and polymerization of N-[4-(cholesteroxycarbonyl)phenyl]maleimide
β Scribed by Tsutomu Oishi; Yuki Otsubo; Koji Matsusaki; Minoru Fujimoto
- Book ID
- 107846941
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 694 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
N-(4-Tetrahydropyranyl-oxy-phenyl) maleimide (THPMI) was prepared and polymerized by radical or anionic initiators. THPMI could be polymerized by 2,2Π-azobis(isobutyronitrile) (AIBN) and potassium tert-butoxide. Radical polymers (poly(THPMI)r) were obtained in 15-50% yields for AIBN in THF at 65Β°C
## Abstract The controlled/living radical polymerization of __N__βphenyl maleimide (NPMI) was achieved using 2,2β²βazobisisobutyronitrile as the initiator and 2βcyanopropylβ2βyl dithiobenzoate as the reversible additionβfragmentation chain transfer agent at 75Β°C in dichloroethane/ethylene carbonate