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Synthesis and polymerization of N-[4-(cholesteroxycarbonyl)phenyl]maleimide

✍ Scribed by Tsutomu Oishi; Yuki Otsubo; Koji Matsusaki; Minoru Fujimoto


Book ID
107846941
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
694 KB
Volume
34
Category
Article
ISSN
0032-3861

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N-(4-Tetrahydropyranyl-oxy-phenyl) maleimide (THPMI) was prepared and polymerized by radical or anionic initiators. THPMI could be polymerized by 2,2Ј-azobis(isobutyronitrile) (AIBN) and potassium tert-butoxide. Radical polymers (poly(THPMI)r) were obtained in 15-50% yields for AIBN in THF at 65°C

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## Abstract The controlled/living radical polymerization of __N__‐phenyl maleimide (NPMI) was achieved using 2,2′‐azobisisobutyronitrile as the initiator and 2‐cyanopropyl‐2‐yl dithiobenzoate as the reversible addition‐fragmentation chain transfer agent at 75Β°C in dichloroethane/ethylene carbonate