Synthesis and Polymerization of cis, cis-1-Methylcyclooctadiene-1,5
โ Scribed by Valvassori, A. ;Sartori, G. ;Turba, V. ;Lachi, M. P.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 461 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0449-2994
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๐ SIMILAR VOLUMES
Fenestranes [1] [fenestra (Lat.), window] are a unique family of compounds with four fused carbocycles that share a central quaternary carbon atom which exhibits planarizing distortion (for example, 1, Scheme 1). [2] By changing ring sizes and ringfusion configurations, variable planarization of the
It was reported recently (3) from this Laboratory that cis-cis-cis-1,4,7-cyclononatriene I is isomerized by potassium t-butoxide (KOBu) in dimethylsulfoxide (DMSO) to the cis-cis-cis-1,3,6:isomer 11 and then to the bicyclic isomer, (4) cis-bicyclo[4. 3.O]nona-P, rl-diene IV. Although cis-cis-cis-1,3