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Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-Azafenestrane with Discovery of an Unexpected Dyotropic Rearrangement

โœ Scribed by Scott E. Denmark; Justin I. Montgomery


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
336 KB
Volume
117
Category
Article
ISSN
0044-8249

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Synthesis of cis,cis,cis,cis-[5.5.5.4]-1
โœ Scott E. Denmark; Justin I. Montgomery ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 336 KB ๐Ÿ‘ 1 views

Fenestranes [1] [fenestra (Lat.), window] are a unique family of compounds with four fused carbocycles that share a central quaternary carbon atom which exhibits planarizing distortion (for example, 1, Scheme 1). [2] By changing ring sizes and ringfusion configurations, variable planarization of the