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Synthesis and physico-chemical properties of the bis(2,3,7,8,12,13,17,18-octakis-(octhylthio)-5,10,15,20-tetraazaporphyrinato)lutetium(III) complex

✍ Scribed by Giampaolo Ricciardi; Francesco Lelj; Francesca Bonosi

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 570 KB
Volume: 215
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)89352-i

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✦ Synopsis

The synthesis and the phyaco-chemlcal properties of the bts 3,7,8,12,13,17,1 S-octakls-(octhylthlo)-5,10,15,20_tetraazaporphynnato)lutetmm(III) double-decker complex, Lu(OOTTAP)~, are described ESR, 'H and "C NMR, UV-vlslble and NIR studies show the radical nature of this compound and suggest that the unpaired electron cannot be asslgned to a specdic tetraazaporphynmc rmg on the time scales available Some relevant UV-vlstble spectroscopic and redox features of Lu(OOTTAP)2 resemble closely those of dlphthalocyanme complexes, while the mtenaty and vlbratlonal structure ofthe NIR spectra are rather remlmscent of those of bls-porphynn systems

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