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The 5/2,3/2 Spin Admixture in the Chloroiron(III) Derivative of the Sterically Crowded 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetraphenylporphyrin

✍ Scribed by Volker Schünemann; Michael Gerdan; Alfred X. Trautwein; Najib Haoudi; Dominique Mandon; Jean Fischer; Raymond Weiss; Alain Tabard; Roger Guilard


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
93 KB
Volume
38
Category
Article
ISSN
0044-8249

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✍ Mathias O. Senge 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 302 KB

Porphyrins with steric hindrance at the periphery are known to exhibit severely non-planar macrocycle conformations. Among other dodecasubstituted porphyrins, the title compound has been studied widely and shows a typical saddle-distorted macrocycle. The specific conformation of the porphyrin leads