Synthesis and physical properties of various organic dyes derived from a single core skeleton, 1,2-dihydroindol-3-one
โ Scribed by Shoji Matsumoto; Daisuke Samata; Motohiro Akazome; Katsuyuki Ogura
- Book ID
- 104095967
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 240 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Various organic dyes were synthesized from 1,2-dihydroindol-3-one analogue via Robinson ring annulation, which proceeded efficiently using DBU as a base to give the p-expanded compounds. These compounds exhibited longer Stokes shifts (over 100 nm) than the 1,2-dihydroindol-3-ones (50-80 nm). Emission peaks of the obtained materials covered the 440-640 nm range.
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## Abstract Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between 6โformylโ2,3โdimethoxybenzoic acid and secondary amines (dibenzylโ or benzyl(isopropyl)amine) in the presence of silica nanoparticles (silica NPs, __ca.__ 70โ nm) proceeds smoothly at room temperature
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