Synthesis and photolysis of 2-formyl-4,4-dimethyl-2,5-cyclohexadienone
✍ Scribed by H. V. Secor; M. Bourlas; J. F. Bardeleben
- Book ID
- 112699001
- Publisher
- Springer
- Year
- 1971
- Tongue
- English
- Weight
- 214 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1420-682X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The photolysis of a heptane solution of 2,6‐di‐__tert__‐butyl‐4‐__tert__‐butylperoxy‐4‐methyl‐ 2,5‐cyclohexadienone (1) with light of 360–480 nm in the presence of 2,6‐di‐__tert__‐butyl‐4‐methylphenol or 2,4,6‐tri‐__tert__‐butylphenol gives rise to their corresponding phenoxyls in a rea
## Abstract Filicinic acid (5) was prepared in 75‐80% overall yield from 4,4‐dimethyl‐2‐cyclohexenone (1). The key intermediate, tetrachlorodienone 2, underwent facile substitution of both β‐chlorine substituents by methoxide affording the bis enol ether 3 which was converted into dichlorofilicinic