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Synthesis and photoconductivity study of phthalocyanine polymers. VI. Ethylenediamine bridged polymeric MnPc

โœ Scribed by Hong-Zheng Chen; Rui-Song Xu; Mang Wang


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
128 KB
Volume
69
Category
Article
ISSN
0021-8995

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โœฆ Synopsis


A novel polymer with quasi-one-dimensional structure of ethylenediamine bridged polymeric manganese phthalocyanine [PcMn(eda)] n was synthesized by complexing of manganese phthalocyanine (MnPc) and ethylenediamine (eda). The structure of the polymer was identified by infrared, ultraviolet-visible, and differential scanning calorimetric analysis. It was found that the polymer [PcMn(eda)] n showed much better photoconductive property than MnPc monomer when [PcMn(eda)] n or MnPc was used as the charge-generation material (CGM)-matched hydrazone charge-transportation material (CTM). Furthermore, the photoconductivities of [PcMn(eda)] n and MnPc were improved if the charge-generation layers (CGLs) were made by electric field poling. All these observations are ascribed to the effects of the one-dimensional molecular structure and the ordered material structure, respectively.


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