An ethylenediamine (eda)-bridged iron phthalocyanine (FePc) polymer [PcFe(eda)] n was synthesized by the complexing of ethylenediamine and FePc. Through electric field poling, a novel low-dimensional [PcFe(eda)] n -PVDF film was obtained. The characterization of the film by DSC, angle-dependent XPS,
Synthesis and photoconductivity study of phthalocyanine polymers. VI. Ethylenediamine bridged polymeric MnPc
โ Scribed by Hong-Zheng Chen; Rui-Song Xu; Mang Wang
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 128 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
A novel polymer with quasi-one-dimensional structure of ethylenediamine bridged polymeric manganese phthalocyanine [PcMn(eda)] n was synthesized by complexing of manganese phthalocyanine (MnPc) and ethylenediamine (eda). The structure of the polymer was identified by infrared, ultraviolet-visible, and differential scanning calorimetric analysis. It was found that the polymer [PcMn(eda)] n showed much better photoconductive property than MnPc monomer when [PcMn(eda)] n or MnPc was used as the charge-generation material (CGM)-matched hydrazone charge-transportation material (CTM). Furthermore, the photoconductivities of [PcMn(eda)] n and MnPc were improved if the charge-generation layers (CGLs) were made by electric field poling. All these observations are ascribed to the effects of the one-dimensional molecular structure and the ordered material structure, respectively.
๐ SIMILAR VOLUMES
A novel polymer with quasi-one-dimensional structure of 4,4-diamino-diphenyl ether bridged polymeric silicon phthalocyanine (I) is synthesized by the condensation polymerization of 4,4-diamino-diphenyl ether (DDE) monomer and dichloride silicon phthalocyanine (Cl 2 SiPc) monomer. The structure of th
The preparation of a novel polymer of ethylenediamine bridged polymeric silicon phthalocyanine ( I) with quasi-one-dimensional structure is described. The product was obtained by the condensation polymerization of ethylenediamine and silicon dichloride phthalocyanine (Cl 2 SiPc) monomers and was cha