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Synthesis and pharmacological activity of conformationally restricted, acetylenic retinoid analogs

✍ Scribed by Roshantha A.S. Chandraratna; Samuel J. Gillett; Tae K. Song; John Attard; Sagar Vuligonda; Michael E. Garst; Taghreed Arefieg; Daniel W. Gil; Larry Wheeler

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 244 KB
Volume: 5
Category: Article
ISSN: 0960-894X
DOI: 10.1016/0960-894x(95)00065-2

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## Abstract Starting from simple aromatic aldehydes and acetylfuran, (__E__)‐1‐(furan‐2‐yl)‐3‐arylprop‐2‐en‐1‐ones (**2**) were synthesized in high yields. Cyclopropanation of the CC bond with trimethylsulfoxonium iodide (Me~3~SO^+^I^−^) furnished (furan‐2‐yl)(2‐arylcyclopropyl)methanones **3** in