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Synthesis and oxidation reactions of a user- and eco-friendly hypervalent iodine reagent

✍ Scribed by Arun P Thottumkara; Thottumkara K Vinod

Book ID
104232258
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
126 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Allylic and benzylic alcohols are cleanly oxidized to the corresponding carbonyl compounds in water or water-THF mixtures using a water-soluble derivative of o-iodoxybenzoic acid. A mechanism involving single electron transfer steps is proposed for this facile and eco-friendly oxidation protocol.

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