Synthesis and Oxidation of Vanadyl Complexes Containing Bispidine Ligands
✍ Scribed by Peter Comba; Shigemasa Kuwata; Gerald Linti; Máté Tarnai; Hubert Wadepohl
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 172 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Chiral racemic rhenium thiolate complexes [CpRe-SCH 2 CH 2 NHAc (8), SCH 2 CH 2 C(O)OH (9). A milder synthesis using hydrated sodium carbonate as a base (NO)(PPh 3 )(SR)] were obtained under either acidic or basic conditions. Thus, when [CpRe(NO)(PPh 3 )(CH 3 )] (1) was provided 8 and compounds with
cyclosilazane structures are assumed. We have now observed that partial isomerizations takeplace in thesereactions which depend strongly on the reaction conditions. The monosilylation of hexamethylcyclotrisilazane with butyllithium/trimethylchlorosilane in diglyme at temperatures between -60 and 1 6