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Optimization of the Efficiency of Oxidation Catalysts Based on Iron Bispidine Complexes

✍ Scribed by Peter Comba; Hubert Wadepohl; Sebastian Wiesner


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
372 KB
Volume
2011
Category
Article
ISSN
1434-1948

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Highly Efficient Amine Organocatalysts B
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## Abstract A highly diastereoselective and enantioselective Michael addition of cyclohexanone, acetone and other ketones to nitroolefins was developed by the use of an amine organocatalyst based on bispidine. Additionally, a theoretical study of transition structures revealed that this bispidine‐b