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ChemInform Abstract: Highly Efficient Amine Organocatalysts Based on Bispidine for the Asymmetric Michael Addition of Ketones to Nitroolefins.

✍ Scribed by Zhigang Yang; Jie Liu; Xiaohua Liu; Zhen Wang; Xiaoming Feng; Zhishan Su; Changwei Hu


Publisher
John Wiley and Sons
Year
2009
Weight
63 KB
Volume
40
Category
Article
ISSN
0931-7597

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Highly Efficient Amine Organocatalysts B
✍ Zhigang Yang; Jie Liu; Xiaohua Liu; Zhen Wang; Xiaoming Feng; Zhishan Su; Changw πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 282 KB πŸ‘ 2 views

## Abstract A highly diastereoselective and enantioselective Michael addition of cyclohexanone, acetone and other ketones to nitroolefins was developed by the use of an amine organocatalyst based on bispidine. Additionally, a theoretical study of transition structures revealed that this bispidine‐b