A Highly Enantioselective Organocatalyst for the Michael Addition of Cyclic Ketones to Nitroolefins.
β Scribed by Ming-Kui Zhu; Lin-Feng Cun; Ai-Qiao Mi; Yao-Zhong Jiang; Liu-Zhu Gong
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 18 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract A highly diastereoselective and enantioselective Michael addition of cyclohexanone, acetone and other ketones to nitroolefins was developed by the use of an amine organocatalyst based on bispidine. Additionally, a theoretical study of transition structures revealed that this bispidineβb