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Synthesis and Novel Reactivity of Halomethyldimethylsulfonium Salts

✍ Scribed by Xu, Yuelian; Fletcher, Michelle; Dolbier, William R.


Book ID
120397204
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
141 KB
Volume
65
Category
Article
ISSN
0022-3263

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Synthesis and reactivity of chiral organ
✍ Patrice Pinsard; Jean-Paul Lellouche; Jean-Pierre Beaucoufi; RenΓ© GrΓ©e πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 250 KB

A short and efficient synthesis of the two enantiomeric iron-complcxed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral fotmyloxirane 3, the corresponding chiral ylides exhibit quite difietent mactivities. Few examples of Wittig-type reactions with phosphotus or sulphur