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Synthesis and Nonlinear Optical Absorption of Novel Porphyrin–Osmium-Cluster Complexes

✍ Scribed by Guo Ying Yang; Siau Gek Ang; Leng Leng Chng; Yiew Wang Lee; Ernest Wei-Pin Lau; Kin Seng Lai; How Ghee Ang

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
127 KB
Volume
9
Category
Article
ISSN
0947-6539

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## Abstract The synthesis of the 1st generation dendrimer 1,3,5‐{__trans__‐[Ru(C≡C‐3,5‐(__trans__‐[Ru(C≡CPh)(dppe)~2~(C≡CC~6~H~4~‐4‐(__E__)‐CHCH)])~2~C~6~H~3~)(dppe)~2~(C≡CC~6~H~4~‐4‐(__E__)‐CHCH)]}~3~C~6~H~3~ proceeds by a novel route that features Emmons‐Horner‐Wadsworth coupling of 1,3,5‐C~6~H