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Synthesis and molecular structures of 1-boracyclopent-2-enes

✍ Scribed by Ezzat Khan; Rhett Kempe; Bernd Wrackmeyer


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
218 KB
Volume
23
Category
Article
ISSN
0268-2605

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Synthesis and molecular structures of 1-
✍ Ezzat Khan; Rhett Kempe; Bernd Wrackmeyer 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 199 KB 👁 2 views

## Abstract The reaction of alkyn‐1‐yl(chloro)(methyl)vinyl‐ and alkyn‐1‐yl(chloro)(phenyl)‐vinylsilane with 9‐borabicyclo[3.3.1]nonane (9‐BBN) afforded selectively 1‐silacyclopent‐2‐ene derivatives containing a SiCl function, as a result of consecutive 1,2‐hydroboration and 1,1‐organoboration. Pr

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A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ‫ס‬ Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ‫ס‬ tBu, RЈ ‫ס‬ Ph (for 2e) (X ‫ס‬ Cl) and R, RЈ ‫ס‬ Et; X ‫ס‬ Br (for 2b). The resulti