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Synthesis and Molecular Structure of Tris(pentamethylphenyl)aluminum, (C6Me5)3Al, and the Magnesium Cluster [Mg6(μ3-OH)2(μ3-Br)2(μ2-Br)8(OEt2)8]

✍ Scribed by Jason K. Vohs; L. Ellen Downs; Jessica Stasalovich; Michael Barfield; Gregory H. Robinson


Book ID
110405042
Publisher
Springer
Year
2002
Tongue
English
Weight
101 KB
Volume
13
Category
Article
ISSN
1040-7278

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Synthesis and structural characterizatio
✍ Chen-Long Lee; Pang-Yen Yang; Chang-Wei Su; Jhy-Der Chen; Lin-Shu Liou; Ju-Chun 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 151 KB

From a solution prepared by a reaction of Mo 2 (O 2 CCH 3 ) 4 with KTp\* (Tp\*= hydridotris(3,5-dimethylpyrazolyl)borate, HB(Me 2 Pz) 3 ), in diglyme at room temperature followed by addition of excess (CH 3 ) 3 SiBr to the red solution in refluxing THF, the complexes [HB(Me 2 Pz) 3 )BH][Br 3 Mo(m-Br