Synthesis and Molecular Structure of Symmetrical 1,8-Diarylnaphthalenes
✍ Scribed by Grégory Pieters; Vincent Terrasson; Anne Gaucher; Damien Prim; Jerôme Marrot
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 366 KB
- Volume
- 2010
- Category
- Article
- ISSN
- 1434-193X
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A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ס Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ס tBu, RЈ ס Ph (for 2e) (X ס Cl) and R, RЈ ס Et; X ס Br (for 2b). The resulti
1191 A "chemical" hint to the existence of a "tight" 4q3e configuration is the finding that the dication produced from [l.l.l.l]isopagodane [2] is reduced by methanol Lo thestarting hydrocarbon(not to the [l.l.l.l]isodiene); the[2.2.1.1] dication 3(4)2 '--like the [1.1.1.1] dication [3]-adds methano