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Synthesis and Molecular Structure of [Cp*Ta(Ph)(P6Ph5)]: A Terminal Phosphinidene Complex of the (P6Ph5)3– Ligand (Cp* = C5Me5)

✍ Scribed by Robert Wolf; Evamarie Hey-Hawkins

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
99 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Organometallic Niobium and Tantalum Complexes with Primary Phosphine Ligands: Syntheses and Molecular Structures of [Cp*MCl4(PH2R)] (M = Nb, Ta; Cp* = C5Me5;R = But, Ad, Cy, Ph, 2, 4, 6-Me3C6H2 (Mes))
✍ Steffen Blaurock; Evamarie Hey-Hawkins 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b