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Single insertion of propene into a cationic zirconium(IV) complex: Isolation and X-ray crystal structure of [(C5Me5)Zr(CH2CHMeCH 2Ph)(CH2Ph)]-[B(CH2Ph)(C6F5)3]

✍ Scribed by Claudio Pellecchia; Attilio Immirzi; Adolfo Zambelli

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
275 KB
Volume
479
Category
Article
ISSN
0022-328X

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## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz