𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and Molecular Structure of a Tripodal Triaminostibine

✍ Scribed by Lutz H. Gade; Bernd Findeis; Olaf Gevert; Helmut Werner

Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
76 KB
Volume
626
Category
Article
ISSN
0372-7874

No coin nor oath required. For personal study only.

✦ Synopsis

Reaction of the tripodal trilithium triamide [MeSi{SiMe 2 N(Li)(p-Tol)} 3 (thf) 2 ] (1) with SbCl 3 in toluene gave the corresponding triaminostibine [MeSi{SiMe 2 N-(p-Tol)} 3 Sb] (2) in good yield. Its [2,2,2]bicyclooctane-related cage structure, comprising the trisilylsilane unit and the triamidostibine fragment, was established by a single crystal X-ray structure analysis: Space group P1, Z = 2, lattice dimensions at 293 K: a = 8.645(4), b = 10.029(5), c = 19.678(9) A Ê , a = 98.50(3)°, b = 97.46(3)°, c = 94.80(3)°, R = 0.0216.

πŸ“œ SIMILAR VOLUMES

Synthesis and Structure of a Hexaazadiph
Synthesis and Structure of a Hexaazadiphosphadiarsatricyclodecane
✍ Prof. Dr. Otto J. Scherer; Dipl.-Chem. Walter GlΓ€ssel; Doz. Dr. Gottfried Huttne πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 237 KB

extensively flatten the molecular skeleton around the nitrogen atoms and that the SiNSi angle (presumably near 120") will therefore change less than the CNC angle. 2) The 14N coupling constant of the tetrakis(trimethylsily1)hydrazine radical cation is at least 3 G smaller than that of analogous tet

Synthesis and Structure of a Cyclopropap
Synthesis and Structure of a Cyclopropapyridine
✍ Dr. Ramesh Bambal; Prof. Dr. Hans Fritz; Grety Rihs; Dr. ThΓ©ophile Tschamber; Pr πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 244 KB
The Azide Homologues EtPPP and PhAsAsAs
The Azide Homologues EtPPP and PhAsAsAs as Bifacially Coordinated Ligands in Tripod-Cobalt Complexes: Synthesis, Structure and Molecular Dynamics
✍ Dipl.-Chem. Annette Barth; Prof. Dr. Gottfried Huttner; Dipl.-Chem. Martin Fritz πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 387 KB

Aryl a ## 6 b [111 Thus, the fact that all NMR signals appear only singly in 5. despite the unsymmetrical structure, cannot be explained in terms of a rapid rmgopening 5 + 4 and renewed conrotatory ring closure. The mechanism required from the Because of the trans arrangement of the sterically ve