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Molecular Structure of a Benzocyclobutadiene

✍ Scribed by Dr. Werner Winter; Dr. Henner Straub


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
220 KB
Volume
17
Category
Article
ISSN
0044-8249

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Reaction of the tripodal trilithium triamide [MeSi{SiMe 2 N(Li)(p-Tol)} 3 (thf) 2 ] (1) with SbCl 3 in toluene gave the corresponding triaminostibine [MeSi{SiMe 2 N-(p-Tol)} 3 Sb] (2) in good yield. Its [2,2,2]bicyclooctane-related cage structure, comprising the trisilylsilane unit and the triamidos