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Synthesis and molecular structure of a novel barium arylspiroboronate ester

✍ Scribed by Nathan R. Halcovitch; Michael J. Geier; Christopher M. Vogels; Andreas Decken; Stephen A. Westcott


Book ID
111488204
Publisher
SP Versita
Year
2011
Tongue
English
Weight
596 KB
Volume
9
Category
Article
ISSN
1895-1066

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Synthesis of β€˜Pear Ester’. A novel synth
✍ GΓΌnther Ohloff; Manfred Pawlak πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 245 KB

## Abstract Vinylogous epoxyaldehydes undergo stereospecific __Wittig__ condensations in high yields. The resulting diolefinic epoxides are cleaved at the C(1)–C(2) single bond, when treated with periodic acid, to give the corresponding aldehydes. Direct transformation into the corresponding ethyl‐