Synthesis and molecular structure of a new family of iridium-(III) and rhodium(III) complexes: [(η5-Me5C5)Ir(LL)X]+ and [(η5-Me5C5)Rh(LL)Cl]+; LL = 2,2′-bipyridine or 1,10-phenanthroline; X = Cl or H. Single crystal structures of [(η5-Me5C5)Ir(bpy)Cl]Cl and [(η5-Me5C5)Rh(phen)Cl]ClO4
✍ Scribed by Marie-Thérèse Youinou; Raymond Ziessel
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 828 KB
- Volume
- 363
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz
## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3