Synthesis and molecular structure of a dinuclear quadruply bridged cobalt(II) compound with a short metal-metal bond, Co2[(p-CH3C6H4)NNN(p-C6H4CH3)]4
โ Scribed by Cotton, F. Albert; Poli, Rinaldo
- Book ID
- 126931587
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 296 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
SUNl4ARY reported. (Co(C0) I (C~HS)ZP-N(CHI) ICH(CH3) (Cdi,)] 1 2 are compared. Synthesis and molecular structure determination of the title compound are The W R spectra of (M~'I~(CO)\*(C~HS)IP-N(CHI) ICH(CH3) (C6Ha)I )Z and CRYSTAL STRUCTURE The crystals are monoclinic with ( I = 11.713(6), b -19.5
The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho