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Synthesis and magnetic properties of transition metal cyclotetraphosphates M2P4O12 (M = Mn, Co, Ni, Cu)

✍ Scribed by W. Gunsser; D. Fruehauf; K. Rohwer; A. Zimmermann; A. Wiedenmann

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
555 KB
Volume
82
Category
Article
ISSN
0022-4596

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New transition metal sul5des BaKCu 3 MS 4 (M ‫؍‬ Mn, Co, Ni) were prepared from BaCO 3 , K 2 CO 3 , and the corresponding transition metal oxides by CS 2 /Ar sulfurization. The materials are based on a common structural pattern consisting of 2-D arrangements of MS 4 tetrahedra linked by edges, cryst