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The Magnetic Properties and Structures of the Transition Metal Pyroarsenates M2As2O7 (M = Ni, Co, Mn)

โœ Scribed by A.M. Buckley; S.T. Bramwell; P. Day; D. Visser


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
291 KB
Volume
115
Category
Article
ISSN
0022-4596

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New transition metal sul5des BaKCu 3 MS 4 (M โ€ซุโ€ฌ Mn, Co, Ni) were prepared from BaCO 3 , K 2 CO 3 , and the corresponding transition metal oxides by CS 2 /Ar sulfurization. The materials are based on a common structural pattern consisting of 2-D arrangements of MS 4 tetrahedra linked by edges, cryst