Four novel manganese(II) binuclear complexes have been prepared and characterized, namely [Mn2(TCPHTA)(L)J-(C104)2 [where L is 2,2'-bipyridyl (bipy), 1,10-phenanthroline (phen), 4,4'-dimethyl-2,2'-bipyridyl (Me2bipy) or 5-nitro-l,10-phenanthroline (NO2-phen) and TCPHTA is the tetrachlorophthalate di
Synthesis and magnetic properties of tetrabromophthalato-bridged manganese(II) binuclear complexes
β Scribed by Ming-Ming Miao; Dia-Zheng Liao; Zong-Hui Jiang; Geng-Lin Wang
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 262 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0340-4285
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A b s t r a c t Six new p-phthalato binuclear oxovanadium(1V) complexes, namely [(VO)z(PHTH)-(L)2]SO, (L denotes '2,2'-bipyridine (bpy); 1,lO-phenanthroline (phen); 4,4'-dimethyl-2,2'-bipyridine (Mezbpy); 5-nitrcz1 ,lO-phenanthroline (NOZ-phen); 5-chIo~1,lO-phenanthroline (C1-phen) and 5methyl-1,lO-
## Abstract A new binucleating bis(terdentate) ligand, 3,5β[3βbis(2βpyridyl)pyrazoleβ1βylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ΞΌβpyrazolato)(ΞΌβhydroxido)βbridged binuclear and tetranuclear complexes [L^2^Cu~2~(ΞΌβOH)(ClO~