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Synthesis and Ligand Properties of a Stable Five-Membered-Ring Vinylidenephosphorane

✍ Scribed by Matthew Asay; Tsuyoshi Kato; Nathalie Saffon-Merceron; Fernando P. Cossío; Antoine Baceiredo; Guy Bertrand

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
356 KB
Volume
120
Category
Article
ISSN
0044-8249

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## Abstract **A single donor substituent** at each terminus is sufficient to make the CCC skeleton of allenes very flexible and give carbon(0) character to the central carbon atom. This allows the synthesis of a four‐membered carbocyclic allene, which can be doubly protonated and behaves as a very