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Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene

✍ Scribed by Mohand Melaimi; Pattiyil Parameswaran; Bruno Donnadieu; Gernot Frenking; Guy Bertrand

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
387 KB
Volume
121
Category
Article
ISSN
0044-8249

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Synthesis and Ligand Properties of a Per
Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene
✍ Mohand Melaimi; Pattiyil Parameswaran; Bruno Donnadieu; Gernot Frenking; Guy Ber πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 387 KB πŸ‘ 1 views

## Abstract **A single donor substituent** at each terminus is sufficient to make the CCC skeleton of allenes very flexible and give carbon(0) character to the central carbon atom. This allows the synthesis of a four‐membered carbocyclic allene, which can be doubly protonated and behaves as a very