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Synthesis and investigation of 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphin and its complexes with manganese (III) acetate and chloride

โœ Scribed by Nikitin, A. A.; Klyueva, M. E.; Semeikin, A. S.; Lomova, T. N.


Book ID
125395697
Publisher
SP MAIK Nauka/Interperiodica
Year
2014
Tongue
English
Weight
367 KB
Volume
50
Category
Article
ISSN
1070-4280

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The configurations and conformations of 5.1 S-dialkyloctaethylporphodimethenes HdOEPRd are described for R = Me. Et, iPr, tBu. The "normal" compounds (1 a to ld) have the syn-axial ("au") configuration, the %nomalous" isomers (2b to 4b) the anti configuration at CS.15. This is proved by a crystal st