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Metal complexes with tetrapyrrole ligands. 30. The manganese-nitrogen triple bond. Synthesis and molecular stereochemistry of (5,15-dimethyl-2,3,7,8,12,13,17,18-octaethyl-5H,15H-porphinato)nitridomanganese(V)

โœ Scribed by Buchler, Johann W.; Dreher, Christine; Lay, Kiong Lam; Lee, Young J.; Scheidt, W. Robert


Book ID
121320765
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
581 KB
Volume
22
Category
Article
ISSN
0020-1669

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Metal Complexes with Tetrapyrrole Ligand
โœ Botulinski, Andreas ;Buchler, Johann W. ;Abbes, Nour Eddine ;Scheidt, W. Robert ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 530 KB

The configurations and conformations of 5.1 S-dialkyloctaethylporphodimethenes HdOEPRd are described for R = Me. Et, iPr, tBu. The "normal" compounds (1 a to ld) have the syn-axial ("au") configuration, the %nomalous" isomers (2b to 4b) the anti configuration at CS.15. This is proved by a crystal st