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Synthesis and Intramolecular Pericyclization of 1-Azulenyl Thioketones

✍ Scribed by Ito, Shunji; Okujima, Tetsuo; Kikuchi, Shigeru; Shoji, Taku; Morita, Noboru; Asao, Toyonobu; Ikoma, Tadaaki; Tero-Kubota, Shozo; Kawakami, Jun; Tajiri, Akio


Book ID
121426347
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
152 KB
Volume
73
Category
Article
ISSN
0022-3263

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Synthesis and Redox Behavior of 1-Azulen
✍ Taku Shoji; Junya Higashi; Shunji Ito; Kozo Toyota; Toyonobu Asao; Masafumi Yasu πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 261 KB πŸ‘ 1 views

## Abstract The reaction of azulenes with several sulfoxides in the presence of acid anhydrides to afford the corresponding 1‐azulenylsulfonium and 1,3‐azulenediyldisulfonium ions is reported. The subsequent conversion of these ions in high yields into 1‐azulenyl methyl and phenyl sulfides and 1,3‐