## Abstract The reaction of azulenes with several sulfoxides in the presence of acid anhydrides to afford the corresponding 1‐azulenylsulfonium and 1,3‐azulenediyldisulfonium ions is reported. The subsequent conversion of these ions in high yields into 1‐azulenyl methyl and phenyl sulfides and 1,3‐
ChemInform Abstract: Synthesis and Redox Behavior of 1-Azulenyl Sulfides and Efficient Synthesis of 1,1′-Biazulenes.
✍ Scribed by Taku Shoji; Junya Higashi; Shunji Ito; Kozo Toyota; Toyonobu Asao; Masafumi Yasunami; Kunihide Fujimori; Noboru Morita
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 34 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Novel ferrocene‐substituted bis(3‐methylthio‐1‐azulenyl)methylium ions **5**^+^ and **6**^+^ were synthesized by the hydride abstraction reaction of the corresponding hydro derivatives **3** and **4** with 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ). Compounds **3** and **4** were r
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