Two kinds of "butterfly-shaped" host compounds, 2,5-bis(triphenylmethyl)hydroquinone (1) and 2,5bis(diphenylmethyl)hydroquinone (2) were designed and synthesized. 1 and 2 can form inclusion complexes with various small organic molecules. These inclusion complexes were determined by 1 H NMR spectrosc
Synthesis and inclusion properties of twelve-membered carbocyclic hosts
β Scribed by David D. MacNicol; Stephen Swanson
- Book ID
- 104235428
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 167 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Trigonal symmetry is a feature encountered in the structures of certain hosts possessing the ability to form crystalline inclusion compounds in which the enclosing structure is consolidated by van der Waals forces alone.
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This review covers the various synthetic routes to the carbocyclic and furanoid fatty acids, and examines numerous refinements to such schemes to improve the yield or to permit extension of the procedure to novel compounds. The occurrence of these unusual fatty acids in nature is also briefly review