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Synthesis and Hydrogenation of Acetonylmalonaldehyde Bis(ethylene acetal) (III).

✍ Scribed by M. M. Vartanyan; A. F. Medvedev; B. I. Ugrak

Publisher
John Wiley and Sons
Year
2006
Weight
14 KB
Volume
37
Category
Article
ISSN
0931-7597

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Carbon–Hydrogen Bond Activation of Arenes by a [Bis(oxazolinyl)phenyl]rhodium(III) Acetate Complex
✍ Jun-ichi Ito; Hisao Nishiyama 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),