Synthesis and hydroboration/oxidation of tricyclo(5.2.1.04,10)dec-8-ene-2,5-dione(bis-acetal): new synthetic entry to tricyclo(5.2.1.04,10)decane-2, 5, 8-trione
✍ Scribed by Elena Carceller; M.Llutsa Garcaía; Felix Serratosa; Manuel Font-Altaba; Xavier Solans
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 784 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
✦ Synopsis
Tricyclo(5.2.1.04~10)dacane-2,S,8-trions (4) has bssn aynthasized from the cortssponding bis-acetal of the unsaturated diketons 20 by a hydroborationloxihationfdaprotsction saquence.
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Although ring-constrained peptide analogs have been reported as tools for enforcing @turn