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Synthesis and Herbicidal Activity of 2α,4α-Dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one Derivatives †

✍ Scribed by Costa, Adilson V.; Barbosa, Luiz Cláudio de A.; Demuner, Antonio J.; Silva, Antonio A.


Book ID
126125980
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
959 KB
Volume
47
Category
Article
ISSN
0021-8561

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irradiation of 8-oxabicyclo[3.2.l]oct-6-en-2-ones results in a 1 ,Sacyl rearrangement. The initial photoproduct undergoes a subsequent reaction involving hydrogen transfer followed by intramolecular cycloaddition of a ketene intermediate.