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ChemInform Abstract: Synthesis of 4α-Hydroxy-6,6-dimethyl-3-oxabicyclo(3.1.0)hexan-2- one from (+)-3-Carene.

✍ Scribed by F. Z. GALIN; O. S. KUKOVINETS; V. V. SHERESHOVETS; R. L. SAFIULLIN; A. G. KUKOVINETS; N. N. KABAL'NOVA; V. G. KASRADZE; R. N. ZARIPOV; T. A. KARGAPOL'TSEVA; YU. A. KASHINA; G. A. TOLSTIKOV

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Novel Conversion of Perfluoro(2,6-dimethyl-1-azacyclohexene) to 3,3,4,4,5-Pentafluoro-2,6-diphenyl-2,6-bis (trifluoromethyl)-1azabicyclo[3.1.0]hexane. -Treatment of perfluoro-azacyclohexene (I) with 2 equiv. of phenyllithium (V) in a cyclohexane/Et 2 O mixture provides access to azabicyclohex