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ChemInform Abstract: Construction of 2,3- and 3,4-Functionalized Silacyclopentanes: Synthesis of 6-Aza-2,2-diphenyl-2-silabicyclo[3.1.0]hexane and 6-Aza-3,3-diphenyl-3-silabicyclo[3.1.0]hexane Derivatives.

โœ Scribed by S. MIGNANI; M. BARREAU; D. DAMOUR; A. RENAUDON; V. DEJEAN; G. MANUEL

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Novel Conversion of
ChemInform Abstract: Novel Conversion of Perfluoro(2,6-dimethyl-1-azacyclohexene) to 3,3,4,4,5-Pentafluoro-2,6-diphenyl-2,6-bis (trifluoromethyl)-1-azabicyclo[3.1.0]hexane.
โœ R. Eric Banks; Mohamed K. Besheesh; Nicholas J. Lawrence; Robin G. Pritchard; Da ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

## Novel Conversion of Perfluoro(2,6-dimethyl-1-azacyclohexene) to 3,3,4,4,5-Pentafluoro-2,6-diphenyl-2,6-bis (trifluoromethyl)-1azabicyclo[3.1.0]hexane. -Treatment of perfluoro-azacyclohexene (I) with 2 equiv. of phenyllithium (V) in a cyclohexane/Et 2 O mixture provides access to azabicyclohex