Highly fluorescent Eu -polymer complexes were synthesized through copolymerization of EuPhen ( Nap ) 2 AA with methyl methacrylate or styrene and their luminescent properties were investigated. The Eu -polymer luminophores showed intense red emission under UV excitation, and the emission intensities
Synthesis and fluorescence properties of the mixed complexes of Eu(III) with polymer ligand and thenoyl trifluoroacetone
β Scribed by Yun-Pu Wang; Yi Luo; Rong-Min Wang; Li Yuan
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 133 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
β¦ Synopsis
The mixed ligand complexes of europium(III) with poly(chloromethyl styrene)-bound 1,4,8,11-tetraazacyclotetradecane (PTACT) and thenoyl trifluoroacetone (TTA) have been synthesized and characterized by Fourier transform infrared and elemental analysis, Inductively Coupled Plasma-Atomic Emission Spectrometry, and X-ray photoelectron spectroscopy. The fluorescence properties of PTACT-Eu-TTA were studied, and it is found that the polymer-mixed ligand complexes emit strong fluorescence at room temperature.
π SIMILAR VOLUMES
Two novel coordination polymers formed by cobalt nitrate and 1,2-bis(4-pyridyl)ethane with the homologous ligands 2aminoterephthalic acid and terephthalic acid, respectively, have been prepared. One displays a fivefold diamond-type feature while the other exhibits a twofold interpenetrating