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Synthesis, Properties, and Structure of a Mononuclear Hydroxoiron (III) Complex of a Porphinoid Ligand System with Bifacial Sterical Hindrance

✍ Scribed by Prof. Dr. Johann W. Buchler; Dr. K. Lam Lay; Dr. Young J. Lee; Prof. Dr. W. Robert Scheidt


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
169 KB
Volume
21
Category
Article
ISSN
0044-8249

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The compounds [Cu II 2 Co III 2 (H 2 dea) 2 (dea) 4 ]X 2 (Solv) n [X = Cl (1), Br (2), SCN (3), O 2 CMe (4), I ( 5); Solv = H 2 O or/and CH 3 OH, DMF, n = 1-4] were synthesised by the reaction of zero-valent copper with cobalt(II) salts in non-aqueous (CH 3 OH, DMF, DMSO) solutions of diethanolamine