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Synthesis and evaluation of a scintillant-containing solid support for use in combinatorial chemistry

✍ Scribed by Bruce Clapham; Andrew J Sutherland


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
88 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


A scintillant monomer, 2,5-diphenyl-4-vinyloxazole, has been synthesised and co-polymerised with 4ethylstyrene, divinylbenzene and 4-vinylbenzyl chloride in the presence of a toluene porogen, to form a scintillant-containing macroporous resin. Despite prolonged exposure to organic solvent, this resin retains the ability to scintillate efficiently in the presence of ionising radiation.


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Optically active, polycarbodiimides 3(a, b & c) with pyridine pendant groups were synthesized using [(R) e 2,2 0 -binaphthoxy] (di-isopropoxy) titanium(IV) catalyst. The polymers were characterized by 1 H and 13 C NMR, and IR. Thermal stability of these polymers (up to 162 C by TGA), allows thermall